Predmet: Course title: UČNI NAČRT PREDMETA / COURSE SYLLABUS PREIZKUŠANJE IN KARAKTERIZACIJA POLIMERNIH MATERIALOV TER ZAGOTAVLJANJE KAKOVOSTI TESTING

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1 Predmet: Course title: UČNI NAČRT PREDMETA / COURSE SYLLABUS PREIZKUŠANJE IN KARAKTERIZACIJA POLIMERNIH MATERIALOV TER ZAGOTAVLJANJE KAKOVOSTI TESTING & CHARACTERIZATION OF POLYMER MATERIALS AND QUALITY ASSURANCE Študijski program in stopnja Study programme and level Študijska smer Study field Letnik Academic year Semester Semester Tehnologija polimerov, 1. stopnja 2 2 Polymer Technology, 1 st level 2 nd 2 nd Vrsta predmeta / Course type Univerzitetna koda predmeta / University course code: Temeljni /Compulsory PKPMZK Predavanja Lectures Seminar Seminar Vaje Tutorial Klinične vaje work Druge oblike študija Samost. delo Individ. work LV 60 4 ECTS Nosilec predmeta / Lecturer: red. prof. dr. Majda Žigon, doc. Dr. Andreas Hausberger / Prof. Dr. Majda Žigon, Assist. Prof. Dr. Andreas Hausberger Jeziki / Languages: Predavanja/Lectures: Slovenski / Slovenian in Angleški/English Vaje/Tutorial: Slovenski / Slovenian in Angleški/English Pogoji za vključitev v delo oz. za opravljanje študijskih obveznosti: Opravljena izpita iz Tehniške matematike in Tehniške fizike. Osnovna znanja o splošni in polimerni kemiji, strokovna angleščina. Prerequisits: Exams Passed Technical Mathematics and Technical Physics. Basic knowledge of general and polymer chemistry, a professional English language.

2 Vsebina: Preizkušanje trdnostnih lastnosti materialov. Neporušitvene preiskave. Materialografija s poudarkom na odkrivanju mikrostrukture polimernih materialov. Preizkusi za ugotavljanje gorljivosti polimernih materialov. Ugotavljanje fizikalnih lastnosti materialov. Opredelitev tehničnih zahtev materiala glede na materialno bazo CAMPUS (posebne, reološke, mehanske, toplotne, električne, splošne in specifične lastnosti ). Testiranje materialov za numerične simulacije. Statistično nadzorovanje procesov. Sistemi zagotavljanja kakovosti. Podatki in statistika. Statistične metode zagotavljanja kakovosti. Meritve (dotične/brezdotične/online/off-line). Pregled tehnik karakterizacije polimerov s praktičnimi primeri: Preliminarni testi in metode ločbe. Spektroskopske tehnike za določanje strukture: UV-VIS, infrardeča (IR) in Ramanska spektroskopija, jedrska magnetna resonanca (NMR), rentgenska difraktometrija (XRD). Termične tehnike za določanje toplotnih lastnosti: diferenčna dinamična kalorimetrija (DSC), ultra hitra DSC, termogravimetrična analiza (TGA), dinamična mehanska analiza Content (Syllabus outline): Testing the strength properties of materials. Non-destructive examination. Metallography, with an emphasis on identifying the microstructure of polymeric materials. Tests for determing the flammability of polymeric materials. Determination of physical properties of polymeric materials. Determination of technical requirements for material regarding CAMPUS database (special, rheological, mechanical, thermal, electrical and other properties, material specific properties ). Material testing for numerical simulations. Statistical process monitoring. Quality assurance systems. Data and statistics. Statistical methods of quality assurance. Measurements (contact/noncontact/online /off-line). Survey of characterization techniques for polymers with practical examples: Preliminary tests and separation methods. Spectroscopic techniques for structure analysis: UV-VIS, infrared (IR) and Raman spectroscopy, nuclear magnetic resonance (NMR), X-ray diffractometry (XRD). Thermal techniques to determine thermal properties: differential scanning calorimetry (DSC), ultra fast DSC (Flash DSC), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA).

3 (DMA). Mikroskopske tehnike za študij morfologije: optična mikroskopija, vrstična in presevna elektronska mikroskopija (SEM, TEM), mikroskopija na atomsko silo (AFM). Microscopic techniques for morphological analysis: optical microscopy, scanning and transmission electron microscopy (SEM, TEM), atomic force microscopy (AFM). Tehnike za določanje električnih lastnosti polimerov: dielektrična spektroskopija (DES), elektrokemijska impedančna spektroskopija (EIS). Techniques for determination of electrical properties of polymers: dielectric spectroscopy (DES), electrochemical impedance spectroscopy (EIS). Reometrija za določanje reoloških lastnosti polimerov. Tehnike za določanje molekulske mase polimerov in njene porazdelitve: velikostna izključitvena kromatografija (SEC), viskozimetrija, sipanje svetlobe (LS), masna spektrometrija (MS). Sklopljene tehnike: SEC-MALS, SEC-IR, SEC-NMR, SEC-MS, 2D HPLC (HPLC- SEC); TGA-MS, TGA-IR, itd. Rheometry to determine the rheological properties of polymers. Techniques for determination of polymer molecular mass and its distribution: size exclusion chromatography (SEC), viscometry, light scattering (LS), mass spectrometry (MS). Hyphenated techniques: SEC-MALS, SEC- IR, SEC-NMR, SEC-MS, 2D HPLC (HPLC- SEC); TGA-MS, TGA-IR, etc. Temeljni literatura in viri / Readings: Knjige/ Books 1. Zupanič F., Križman A., Gradiva: Praktikum, Maribor: Univerza v Mariboru, Fakulteta za strojništvo, Vojvodič Tuma J., Mehanske lastnosti kovin, Ljubljana: Univerza v Ljubljani, Fakulteta za gradbeništvo in geodezijo, Starbek M., Kušar J., Menart D., Celovito obvladovanje kakovosti TQM. Ljubljana: Univerza v Ljubljani, Fakulteta za strojništvo, LAPS, Sluga A., Metljak D., Računalniško podprto obvladovanje kakovosti: program tematskih delavnic. Ljubljana: Univerza v Ljubljani, Fakulteta za strojništvo, LAKOS, Shah V., Handbook of Plastics Testing and Failure Analysis, 3rd Ed.; Hoboken, New Jersey: J.Wiley&Sons, Inc., Crompton T. R., Characterisation of Polymers, Vol. 1. Shawbury: Smithers Rapra Technology Ltd., Campbell D., White J. R., Polymer Characterization, Physical Techniques. London: Chapman&Hall, Cilji in kompetence: Objectives and competences:

4 Predmetno specifični cilji in kompetence: Študent pozna in razume navedene vsebine predmeta in jih zna uporabiti za razlago opazovanj in logično reševanje problemov, povezanih z vsebino predmeta. Študent zna rešiti kvantitativne probleme, povezane s podanimi vsebinami/ zna reševati naloge in enostavne kvantitativne probleme. Študenti osvojijo teoretična in praktična znanja s področja instrumentalnih metod za karakterizacijo polimerov. Študenti so sposobni izbrati ustrezne tehnike / metode za rešitev specifičnega problema iz prakse. Predvideni študijski rezultati: Znanje in razumevanje: Študenti dosežejo zastavljene cilje predmeta. Študenti so usposobljeni, da pridobljeno znanje uporabijo na področju svojega dela in sorodnih področij ter pri optimizaciji laboratorijskih in industrijskih postopkov in procesov. Študenti so sposobni primerjati rezultate z rezultati iz literature, jih preučiti, ustrezno razložiti in povzeti ugotovitve. Metode poučevanja in učenja: predavanja demonstracija računalniške in video predstavitve praktikum Pogoji za pristop k izpitu: 50% prisotnost na predavanjih 100% prisotnost na praktikumu Oddana poročila o laboratorijskih vajah Subject-specific objectives and competences: Students know and understand the contents of the subject and know how to apply them for interpretation of observations and logical problem solving related to the subject matter. Students know how to solve quantitative problems related to the given contents / can solve simple quantitative tasks and problems. Students acquire theoretical and practical knowledge and understanding about instrumental techniques for characterization of polymers. Students are able to choose appropriate methods / techniques to solve specific problems from practice. Intended learning outcomes: Knowledge and understanding: Students will achieve the objectives of the course. Students will be able to use the acquired knowledge in the field of their work and related fields, as well as for the optimization of laboratory procedures and industrial processes. Students will be able to compare their results with those from literature, to examine results critically, to provide relevant explanation and to draw conclusions. Learning and teaching methods: lectures demonstration computer and video presentations practicum Conditions for accession to the exam: 50% attendance at lectures 100% attendance at practicum reports on laboratory work Načini ocenjevanja: Delež (v %) / Weight (in %) Assessment:

5 Skupno oceno predmeta sestavljajo: pisni izpit ustni izpit Final grade consists of: written exam oral examination Reference nosilca / Lecturer's references: Red. prof. dr. Majda Žigon (1) Pedagoško delo: nosilka in izvajalka predmetov na dodiplomskem študiju Univerze v Ljubljani (UL), Fakultete za kemijo in kemijsko tehnologijo FKKT (praktikum pri predmetu Karakterizacija materialov, polimerna kemija v sklopu predmeta Organska kemijska tehnologija), Akademije za likovno umetnost in oblikovanje (Tehnologija plastike) ter Visoke šole za tehnologijo polimerov v Slovenj Gradcu VŠTP (Polimerno inženirstvo, Uvod v polimerne materiale) nosilka in izvajalka predmetov na podiplomskem študiju UL FKKT (praktikum pri predmetu Karakterizacija polimerov z instrumentalnimi metodami, Struktura in stereokemija polimerov) in VŠTP (Lastnosti in karakterizacija polimernih materialov); mentorica in somentorica diplomantom, magistrantom in doktorandom na do- in podiplomskem študiju UL FKKT in VŠTP (2) Strokovno delo : vodja več nacionalnih raziskovalno-razvojnih projektov in projektov za industrijo recenzentka raziskovalnih projektov za slovensko, češko, slovaško, poljsko, belgijsko, hrvaško in srbsko agencijo za raziskovalno dejavnost ter za projekte EU - Marie Curie recenzentka za mednarodne znanstvene revije organizatorica kongresa Evropske polimerne federacije (EPF-2007) v Portorožu in Avstrijsko-slovenske polimerne konference (ASPM-2013) na Bledu (3) Raziskovalno delo: vodja nacionalnih temeljnih in aplikativnih raziskovalnih projektov (polimeri in polimerni materiali s posebnimi lastnostmi), bilateralnih raziskovalnih projektov s Francijo, Češko in Hrvaško (lastnosti polimerov v trdnem stanju in raztopini, novi konjugirani polimeri, prepletene polimerne mreže, polimerni kompoziti in nanokompoziti); vodja slovenske raziskovalne skupine v projektu INCO-Copernicus (visoko razvejeni poliestri in poliuretani) in evropski mreži odličnosti Nanofun-Poly (visoko razvejeni poliestri, polimerni nanokompoziti z nano ZnO in montmorilonitom). (4) Priznanja in sodelovanje v mednarodnih organizacijah: univerzitetna Prešernova nagrada za študente (1974); nagrada Sklada Borisa Kidriča (1989); predsednica Sekcije za polimere Slovenskega kemijskega društva ( ); predsednica Evropske polimerne federacije (EPF) ( ) in predstavnica Sekcije za polimere Slovenskega kemijskega društva v EPF ( ); članica znanstvenega odbora EU mreže odličnosti Nanofun-poly ( ); nacionalna predstavnica in pridružena članica polimerne sekcije IUPAC ( );

6 predsednica strokovnega sveta Centra odličnosti Polimerni materiali in tehnologije (CO PoliMaT) ( ); predsednica Polimerne mreže osrednje in vzhodne Evrope (CEEPN) (2012). (5) Pomembnejša dela/ Selected publications: G. Ambrožič, J. Šribar, S.D. Škapin, M. Žigon, Z. Crnjak Orel. An Antibacterial Macroporous Polyurethane Hybrid Material with a High Content of Zinc Ions: A Template to Uniform ZnO Nanoparticles. Mater. Res. Bulletin, 2013, 48, Žagar E., Žigon M. Aliphatic Hyperbranched Polyesters Based on 2,2- Bis(methylol)propionic Acid Determination of Structure, Solution and Bulk Properties. Prog. Polym. Sci. 2011, vol. 36, pp Alojz Anžlovar, Zorica Crnjak Orel, Majda Žigon. Poly(methyl methacrylate) composites prepared by in situ polymerization using organophillic nano-to-submicrometer zinc oxide particles, Eur. Polym. J. 2010, 46, doi: /j.eurpolymj Žigon M. Uvod v polimere: zapiski predavanj. Ljubljana: Kemijski inštitut, Doc. Dr. Andreas Hausberger (1) Pedagoško delo: - predavatelj predmetov na dodiplomski stopnji na področju tehnologije polimerov/usposabljanje polimernih testov, Del: Mehanska karakterizacija polimernih površin, Inštitut za materialne vede in testiranje polimerov, LV , Montanuniversität Leoben ( ) - Predavatelj predmeta Lastnosti polimerov in obnašanje komponent, Del: Polimerna tribologija, Inštitut za materialne vede in testiranje polimerov, LV , Montanuniversität Leoben ( ) (2) Raziskovalno delo: - vodja in raziskovalec na projektih in programih (COMET K1, Most in proizvodnja prihodnosti), ki sta jih financirala avstrijska vlada (Avstrijska agencija za spodbujanje raziskav, FFG) in industrija. (3) Izbrane publikacije: - Hausberger, A., Major, Z., Theiler, G., Gradt, T. (10/2018). Observation of the adhesive- and deformation- contribution to the friction and wear behaviour of thermoplastic polyurethanes, Wear, Vol , pp 14 22, DOI: /j.wear Thirumalai, S., Hausberger, A., Lackner, J. M., Waldhauser, W., Schwarz, T. (03/2018). "Anode layer source plasma-assisted hybrid deposition and characterization of diamond-like carbon coatings deposited on flexible substrates", Thin Solid Films, Vol. 655, pp 54-61, DOI: https//doi.org/ /j.tsf Haba, D., Hausberger, A., Brunner, A. J. (02/2017). "Flaky and fullerene-like WS2 nanoparticles as tribologic and toughening additives for epoxy", Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, Vol. 231, pp 55-61,DOI: / Manhart, J., Lenko, D., Mühlbacher, I., Hausberger, A., Schaller, R., Holzner, A., Kern, W., Schlögl, S. (1/2015). "Photo-patterned natural rubber surfaces with tunable tribological

7 properties", European Polymer Journal, Vol. 66, pp (DOI: /j.eurpolymj Lecturer's references Prof. Dr. Majda Žigon (1) Teaching: Lecturer at undergraduate study at the University of Ljubljana (UL), Faculty of Chemistry and Chemical Technology, FCCT (Practicum at Materials Characterization, Polymer Chemistry within the subject Organic Chemical Technology), Academy of Fine Arts and Design (Plastics Technology) and at Polymer Technology College (Polymer Engineering and Introduction to Polymeric materials); Lecturer at graduate study at UL FCCT (Practicum for Polymer Characterization Using Instrumental Methods, Polymer Structure and Stereochemistry) and Polymer Technology College (Properties and Characterization of Polymers and Polymeric materials); mentor/supervisor to undergraduate (B.Sc.) and graduate students (M.Sc., Ph.D.). (2) Professional work: Project leader of national research & development projects and industrial projects; Reviewer of research projects for the Slovenian, Czech, Slovak, Polish, Belgian, Croatian and Serbian Research Agencies and for EU projects - Marie Curie actions; Reviewer for international scientific journals; Organizer of the European Polymer Congress in Portorož (EPF-2007) and Austrian- Slovenian Polymer Meeting in Bled (ASPM-2013). (3) Research work: Project leader of national basic and applied research projects (specialty polymers and polymeric materials), bilateral research projects with France, Czech Republic, Croatia (solid state and solution properties of polymers, new conjugated polymers, interpenetrating polymer networks, polymer composites and nanocomposites) ; Project leader of the Slovenian research group in the INCO-Copernicus project (hyperbranched polyesters and polyurethanes) and EU Network of Excellence Nanofun- Poly (hyperbranched polyesters, nanocomposites with nano ZnO and montmorillonite). (4) Awards and participation in international organizations: University Prešeren Award for students in 1974, Boris Kidrič Fund Award in 1989, President of the Section for Polymers (SP) at Slovenian Chemical Society, ; President of the European Polymer Federation (EPF), ; representative of SP at Slovenian Chemical Society to EPF, ; Member of the Scientific Board of the Network of Excellence Nanofun-poly, ; National representative and associate member of the IUPAC Polymer Section, ; President of the Expert Council at the Centre of Excellence for Polymeric Materials and Technologies (CO PoliMaT), ; President of the Central and East European Polymer Network (CEEPN), 2012.

8 (5) Selected publications: Kos T., Anžlovar A., Pahovnik D., Žagar E., Crnjak Orel Z., Žigon M. Zinc-containing block copolymer as a precursor for the in situ formation of nano ZnO and PMMA/ZnO nanocomposites. Macromolecules 2013, vol. 46, pp DOI: /ma Žagar E., Žigon M. Aliphatic Hyperbranched Polyesters Based on 2,2- Bis(methylol)propionic Acid Determination of Structure, Solution and Bulk Properties. Prog. Polym. Sci. 2011, vol. 36, pp Mav Golež I., Pahovnik D., Žigon M., Vohlídal J. Copolymers of 2-methoxyaniline with 2- and 3-aminobenzenesulfonic acid, and 2- and 3-aminobenzoic acid. The effect of reaction conditions on the structure and the properties. Synth. Met. 2011, vol. 161, pp doi: /j.synthmet Huskić M.. Žigon M. PMMA/MMT nanocomposites prepared by one-step in situ intercalative solution polymerization, Eur. Polym. J. 2007, vol. 43, pp Žigon M. Uvod v polimere: zapiski predavanj. Ljubljana: Kemijski inštitut, Assist. Prof. Dr. Andreas Hausberger (1) Teaching: - lecturer of subjects at undergraduate level at Polymer Technology Training polymer testing, Part: Mechanical characterisation of polymer surfaces, Institute of material science and testing of polymers, LV , Montanuniversität Leoben ( ) Lecture, Polymer properties and component behaviour Part: Polymer Tribology, Institute of material science and testing of polymers, LV , Montanuniversität Leoben ( ) (2) Research: - leader and researcher on the projects and programs (COMET K1, Bridge and Production of the Future) financed by the Austrian Government (Austrian Research Promotion Agency, FFG) and industry. (3) Selected publications: - Hausberger, A., Major, Z., Theiler, G., Gradt, T. (10/2018). Observation of the adhesive- and deformation- contribution to the friction and wear behaviour of thermoplastic polyurethanes, Wear, Vol , pp 14 22, DOI: /j.wear Thirumalai, S., Hausberger, A., Lackner, J. M., Waldhauser, W., Schwarz, T. (03/2018). "Anode layer source plasma-assisted hybrid deposition and characterization of diamond-like carbon coatings deposited on flexible substrates", Thin Solid Films, Vol. 655, pp 54-61, DOI: https//doi.org/ /j.tsf Haba, D., Hausberger, A., Brunner, A. J. (02/2017). "Flaky and fullerene-like WS2 nanoparticles as tribologic and toughening additives for epoxy", Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, Vol. 231, pp 55-61,DOI: / Manhart, J., Lenko, D., Mühlbacher, I., Hausberger, A., Schaller, R., Holzner, A., Kern, W., Schlögl, S. (1/2015). "Photo-patterned natural rubber surfaces with tunable tribological

9 properties", European Polymer Journal, Vol. 66, pp (DOI: /j.eurpolymj